Lithium cation conducting TDI anion-based ionic liquids
نویسندگان
چکیده
منابع مشابه
Lithium cation conducting TDI anion-based ionic liquids.
In this paper we present the synthesis route and electrochemical properties of new class of ionic liquids (ILs) obtained from lithium derivate TDI (4,5-dicyano-2-(trifluoromethyl)imidazolium) anion. ILs synthesized by us were EMImTDI, PMImTDI and BMImTDI, i.e. TDI anion with 1-alkyl-3-methylimidazolium cations, where alkyl meant ethyl, propyl and butyl groups. TDI anion contains fewer fluorine ...
متن کاملCation/anion associations in ionic liquids modulated by hydration and ionic medium.
In order to understand the unique solvation and conduction properties of ionic liquids (ILs), we explore their interionic associations modulated by hydration level and ionic medium. Pulsed-field-gradient NMR allows sensitive measurement of separate cation and anion diffusion coefficients, which combine to reflect ionic aggregation. With increasing hydration of ILs, the anomalous ratio of cation...
متن کاملSurface tensions of imidazolium based ionic liquids: anion, cation, temperature and water effect.
This work addresses the experimental measurements of the surface tension of eight imidazolium based ionic liquids (ILs) and their dependence with the temperature (288-353 K) and water content. The set of selected ionic liquids was chosen to provide a comprehensive study of the influence of the cation alkyl chain length, the number of cation substitutions and the anion on the properties under st...
متن کاملConducting organic-metallic composite submicrometer rods based on ionic liquids.
Molecular self-assembly is an emerging subdiscipline of material science with important potential technological applications. Self-assembly is known in both molecular chemistry (for example, aggregation of molecules, molecular crystal or phase-separated polymers) and biology (for example, bilayer formation, protein folding and unfolding). Molecular self-assembly typically relies on amphiphilic ...
متن کاملSurface Tensions of Bis(trifluoromethylsulfonyl)imide Anion-Based Ionic Liquids
Experimental measurements of the surface tension of six imidazolium-, pyridinium-, pyrrolidinium-, and phosphonium-based ionic liquids (ILs) with NTf2 as the common anion and their dependence with the temperatures of (293 to 353) K at atmospheric pressure are presented. The set of selected ILs was chosen to investigate the influence of the length and position of the cation alkyl chain and the c...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Phys. Chem. Chem. Phys.
سال: 2014
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c3cp55354j